Rey Misterio Jr.
The most unlikely selection on this list, Misterio was not renowned for his toughness or martial arts background. It is entirely possible that he would not have had the mindset to make a living competing in fistfights. Few would think of the diminutive masked luchador when considering pro wrestlers best suited for MMA.
Misterio might not have had the interest or ability to take to MMA, but with time and desire, he might have done quite well for himself. So he does not look the part. One might say the same for Demetrious Johnson or Joseph Benavidez.
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